If you need to add custom headers to your volley requests, you can’t do this after initialisation, as the headers are saved in a private variable.

Instead, you need to override the getHeaders() method of Request.class as such:

new JsonObjectRequest(REQUEST_METHOD, REQUEST_URL, REQUEST_BODY, RESP_LISTENER, ERR_LISTENER) {
    @Override
    public Map<String, String> getHeaders() throws AuthFailureError {
        HashMap<String, String> customHeaders = new Hashmap<>();

        customHeaders.put("KEY_0", "VALUE_0");
        ...
        customHeaders.put("KEY_N", "VALUE_N");

        return customHeaders;
    }
};

Explanation of the parameters:

If you want to build a custom request, you can add the headers in it as well:

public class MyCustomRequest extends Request {
    ...
    @Override
    public Map<String, String> getHeaders() throws AuthFailureError {
        HashMap<String, String> customHeaders = new Hashmap<>();

        customHeaders.put("KEY_0", "VALUE_0");
        ...
        customHeaders.put("KEY_N", "VALUE_N");

        return customHeaders;
    }
    ...
}