If you want to upload .ipa file to itunesconnect without integrating developer account in Xcode and you want to use application loader. then you can generate .ipa with iTunes .

Step 1 :- Select device inplace of simulator.

http://i.stack.imgur.com/Xq6iC.png

Step 2 :- Go to Product -> select Archive

http://i.stack.imgur.com/9h28M.png

Step 3 :- After complited process right click to your Archive -> and select show in Finder

http://i.stack.imgur.com/9jofK.png

Step 4 :- when you click on show in finder you will redirect to Archive folder, looks like this

http://i.stack.imgur.com/RlIU8.png

Step 5 :- Right click on .xarchive file -> select Show in finder option.

http://i.stack.imgur.com/hhtc1.png

Step 6 :- Go to Product Folder -> Application Folder -> You will find yourprojectname.app

http://i.stack.imgur.com/KHoiu.png

Step 7 :- Now to convert .app to .ipa just drag and drop into itunes . check below image ,

http://i.stack.imgur.com/udTTp.gif

Step 8 :- Now put this .ipa file in safe place and use when upload with application loader .

Note :- if you want to know how to upload app with application loader then check this ,

Upload app with application Loader

EDIT :-

WARNING :- Don’t make .ipa with changing extension from .aap to .zip and .zip to .ipa.